The atomic groups attached to the nitrogen atoms may be of any organic. The two compounds, which can be viewed as being composed. We have investigated the photophysical, photochemical and electrochemical properties of two bis azo derivatives, e,e. Pdf synthesis and spectroscopic study of naphtholic and. Reduction azides are reduced to tinsubstituted amines by reaction with tin hydrides. Novel compounds 222hydroxy4nitrophenyl hydrazono1,3diphenyl propane1,3dione and 222hydroxy4nitrophenyl hydrazono1phenyl butane1,3dione are prepared on the. Pdf new directions in the chemistry of azocompounds. Our interest in this molecule stems from its ability to act as a diamine. Antioxidant activity study hala s alatbi, bushra k alsalami and iqbal j alassadi university of basrah,college of science, department of chemistry,basrahiraq. Applying different extraction procedures and different analytical technologies toxicological assessment.
The study indicated that the type of lateral groups and their position adversely affects the mesomorphic properties of these compounds. General procedure for the synthesis of amides from azo compounds by smticl 4. Study of removal techniques for azo dyes by biosorption. Synthesis of most azo compounds involves diazotization of a primary aromatic amine. Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated. Developing a method for the analysis of azo dyes using the. However, such compounds are seldom used as polymerization initiators and further discussion on this subject is beyond the scope of this chapter. Azo group is stabilised by becoming part of extended delocalised. New directions in the chemistry of azocompounds research. But in our study, all the spectral data show that 2substituted phenyl azo 4,6. A green dehydrogenation of hydrazo compounds using basic alumina or kfalumina under solventfree conditions afforded azo compounds in good to excellent yields.
Synthesis, azo compounds, guanine and, biological activity, bacteria introduction azo ligands of heterocyclic. A number of studies have shown that, in aqueous media, many azodyes, and. Azo dyes are organic compounds bearing the functional group r. The azo components used were 8hydroxyquinoline, resorcinol, pyrogallol, and 7iodo8hydroxy5. Hence, a series of naphtholic azo dyes 19 were synthesized via diazotization of substituted aniline. The environmental, health and economic impacts of textile. A study of the inhibition of tumor growth in mice and rats with azo compounds. Azo compounds as a family of organic electrode materials.
The unit containing the nitrogennitrogen double bond is called an azo group. Biological studies of syntheised azo compounds of indole. Where r and r are arene groups more stable than alkyl groups. Synthesis and characterization of azo compounds and study. Biodegradation of azo dye compounds kamlesh shah department of biotechnology, p. Molecules 2010, 15 5625 synthesis of azo compounds a3h, a3oh, a3ch3, a 3f, a3cl and a2cl diazotization of anilines a solution of pchloroaniline 10 mmol and 3m hcl 8 ml was heated gently, then water 10 ml was added in order to dissolve the solid. The nature of the aromatic substituents on both sides of the azo group controls the colours of the azo compounds as well as. The mixture was cooled to 0 c in an ice bath with stirring. When the reactivity of the aryl group is increased by the presence of electron donor substituents or fused rings, the direct cn bond formation leads to. Density functional study cavus ms 1, gur m 2, vurdu cd 1, kocaokutgen h 4, sayiner g 3 and kandemirli f 1. Defining threshold levels for the extracted compounds compliance. As well as the study was achieved through the complexes formed between these a new prepared symmetrically azo dyes. Mostly, synthesis of azo compounds involves diazotization of substituted primary. Journal of chemical and pharmaceutical research, 2016, 85.
The antibacterial activities of the compounds were studied using gram positive and gram negative microorganism. The most important contribution of azo compounds to radical chemistry is in their role as reaction initiators. Further work on transformation of the cobaltii complex of 2. Synthesis, characterization of new azo compounds and their. Synthesis of azo compounds organic chemistry portal. Variation in molecular stacking resulting from the different polarity of liquid crystalline molecules. They are compound bearing the functional group rnnr in which r and r can be either alkyl or aryl groups. Azo compounds are compounds bearing the functional group diazenyl r. Studies on synthesis and spectral characterization of some. A detailed theoretical uv study of some azo acrylate compounds. Compounds containing one or more azo groups nn linked to two carbon atoms have a variety of uses. Compounds 183 are convenient photochemical azo precursors.
Synthesis of some azo compounds and a study of their. Azo dyes represent the largest production volume of dye chemistry. Azo dye release in industrial effluent can also have an impact on human health in certain countries. On the chargetransfer excitations in azobenzene maleimide. Azo dyes represent vital components to the fabrics and textiles industries, and diazonium salts are the building blocks that these compounds are made from. Azo compounds as a family of organic electrode materials for alkaliion batteries chao luoa, oleg borodinb, xiao jia,c, singyuk houa, karen j.
Azo dyes are class of compounds containing a nn double bond generally connected to aromatic ring, due to their ability to absorb visible light and ease of. Irradiation at 254 nm photochemically cleaves the ring and the resulting azo compounds often absorb little at these wavelengths and the. Photoswitchable systems with chargetransfer ct transitions have gained much attention during the recent years because of their many emerging applications. In the following, we have summarized some recent syntheses of azo dyes and.
Variation in molecular stacking resulting from the. Some of the azo compounds are studied as hiv inhibitors of viral replications25. In general azo resorcinol compounds can exist in azo hydrazone tautomeric forms. The study indicated that the type of lateral groups and their position adversely. Biodegradation of azo dye compounds premier publishers. New azo mesogenic compounds with oh, ch 3, cl, and f side groups on the central benzene nucleus were synthesized. Synthesis and characterization of azo compounds and study of the. Study on the reactions of azo compounds with acyl halides. Reduction azides are reduced to tinsubstituted amines by. It exists mainly as the trans isomer, but upon illumination.
Study the electrical conductivity for a new azo compound. A detailed theoretical uv study of some azoacrylate. Photochemical and electronic properties of conjugated bis. Synthesis, spectroscopic, thermodynamics and kinetics. Pdf on aug 1, 2011, omer rasheed published new directions in the chemistry of azocompounds find, read and cite all the research you. Potential for use as sonodynamic sensitizers for cell killing. They are a commercially important family of azo compounds, i. The azo components used were 8hydroxyquinoline, resorcinol, pyrogallol, and 7iodo8hydroxy5quinolinesulfonic acid, while the diazol components were sulfanilamide and a number of its derivatives. Azo compounds are very important molecules and have attracted much attention in both academic and applied research 1520. Classifications, properties, recent synthesis and applications of azo. Epr spin trapping study of the decomposition of azo compounds in aqueous solutions by ultrasound.
Azo compound, any organic chemical compound in which the azo group. Combinatorial synthesis of azo dyes linfield college. Gaskelld, xiulin fana, ji chena, tao denga, ruixing. Epr spin trapping study of the decomposition of azo. Synthesis of some azo compounds and a study of their properties. Azobenzene is the prototypical aromatic azo compound. Synthesis and identification symmetrically azo dyes. Azo dyes are extremely important in variety of industries for variety of technical purposes. Preparation of azo compounds for the study of inhibition. Most common method variables are column chemistry stationary phase. Aldamineheterocyclic ligands have been prepared through condensation step to formation aldamine compound as a starting compound for production all ligands in this study, which is used in. Gromova, practical manual of spectrophotometry and. Asian journal of research in chemistry and pharmaceutical. Under nitrogen atmosphere, 1 mmol of azo compound 1 dissolved in dry thf 1 ml was added to the solution.